𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The isomers of diazomethane

✍ Scribed by J.B. Moffat


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
210 KB
Volume
52
Category
Article
ISSN
0022-2860

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Gas-Phase Generation and Characterizatio
✍ Norman Goldberg; Andreas Fiedler; Helmut Schwarz 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 German ⚖ 420 KB

## Abstract A new isomer of diazomethane 1, the nitrile imine, HCNNH (2) is reported to be a stable molecule in the gas phase. Upon neutralizing the α‐distonic HCNNH^+^ cation in a beam experiment, this long‐time predicted ylide can be generated. The experiments are supported by theoretical calcula

The Rates of Diazomethane Formation from
✍ Michael Pearce 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 267 KB

## Abstract The rate of hydrolysis of __N__‐methyl‐__N__‐nitrosoamides by aqueous alkalis varies greatly. Methylnitrosourea **(1)** is hydrolyzed rapidly by aqueous KOH‐solutions at low temperatures to give a high yield of diazomethane. Under similar conditions, __N,N__′‐dimethyl‐__N,N__′‐dinitroso