The isomers of diazomethane
✍ Scribed by J.B. Moffat
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 210 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-2860
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## Abstract A new isomer of diazomethane 1, the nitrile imine, HCNNH (2) is reported to be a stable molecule in the gas phase. Upon neutralizing the α‐distonic HCNNH^+^ cation in a beam experiment, this long‐time predicted ylide can be generated. The experiments are supported by theoretical calcula
## Abstract The rate of hydrolysis of __N__‐methyl‐__N__‐nitrosoamides by aqueous alkalis varies greatly. Methylnitrosourea **(1)** is hydrolyzed rapidly by aqueous KOH‐solutions at low temperatures to give a high yield of diazomethane. Under similar conditions, __N,N__′‐dimethyl‐__N,N__′‐dinitroso