Several complexes containing the Ru-H bond were synthesized according to previous reports: RuH(NO)(PPh 3 ) 3 (I) (1), RuHCl(PPh 3 ) 3 (s)(II) (2), RuHCl(CO)(PPh 3 ) 3 (II) (3), RuH(CH 3 COO)(PPh 3 ) 3 (II) (4) and RuH 2 (CO)(PPh 3 ) 3 (II) (5), and characterized by 1 H NMR and IR spectra; the comple
The isomerization of olefins by palladium complexes
β Scribed by M.B. Sparke; L. Turner; A.J.M. Wenham
- Book ID
- 113172869
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- English
- Weight
- 568 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0021-9517
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
An efficient isomerization of aliphatic and cyclic olelins is achieved by using well-defined metallocene alkyne complexes as catalysts. Titanocene complexes isomerize I-alkenes to internal alkenes under mild conditions. The titanium complex was recovered quantitatively. Cyclic olcfins, e.g. cyclohex
Ε½ . w Ε½ . x The Group 10 complex trans-Pd C H CN Cl and acidic solutions of Ni P OEt effectively catalyze the stereoselec-6 5 2 2 3 4 w Ε½ . x tive isomerization of C5C double bonds in olefinic esters. With acidic solutions of Ni P OEt , only 4-pentenoate is 3 4 produced from 3-pentenoate at early t