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The isomerization of (benzyl thiocyanate)chromium tricarbonyl to isothiocyanate

โœ Scribed by A. Ceccon


Book ID
108347230
Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
170 KB
Volume
29
Category
Article
ISSN
0022-328X

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Experimental and theoretical studies on
โœ M. Kotani; Y. Shigetomi; M. Imada; M. ลŒki; M. Nagaoka ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 231 KB ๐Ÿ‘ 2 views

The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr