The isomerization of 1-butene catalyzed by tetrakis-(triphenylphosphine)dirhodiumdichloride
✍ Scribed by Flaviano D'Amico; Jörn von Jouanne; Hartwig Kelm
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 824 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0304-5102
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The double bond isomerization of butene catalyzed by 1-ethyl-3-methyl-imidazolium chloride ionic liquid has been examined by performing density functional theory calculations at the B3LYP/6-31G (d, p) level. The stepwise H-migration pathway is compared with the concerted H-migration pathway proposed