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The isolation and structure analysis of 2-(2-cyanoethyl)-3-isoxazolin-5-one, 2-(β,D-glucopyranosyl)-3-isoxazolin-5-one and 2-carboxymethyl-3-isoxazolin-5-one from Lathyrus odoratus

✍ Scribed by L. Van Rompuy; F. Lambein; R. De Gussem; R. Van Parijs

Book ID
119405573
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
235 KB
Volume
56
Category
Article
ISSN
0006-291X

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✍ Yosuo Makisumi; Takashi Sasatani 📂 Article 📅 1969 🏛 Elsevier Science 🌐 French ⚖ 178 KB

In continuation of our studies of 3,3-sigmatropic reactions, we have discovered the facile amino-Claisen rearrangement of the N-allyl-enamine system in pyrazolin-5-ones (1). Recent reports (2, 3,4) on the analogous examples of the amino-Claisen rearrangement prompt a preliminary report of our work o