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The IR spectra of the CH3CO+ and CD3CO+ ions

โœ Scribed by P.N. Gates; D. Steele

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
633 KB
Volume
1
Category
Article
ISSN
0022-2860

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Ab initio SCF MO calculations of the electronic structure of Mn(CO)sH and Mn(CO)sCH 3 predict small (< 0.4 eV) splitting between the metal e and b2 orbitals and lead to a new interpretation of their photoelectron spectra which does not necessitate invoking 7r back-bonding to the -CH 3 group in the c