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The Iodine Atom Transfer Addition Reaction (I-ATRA) Initiated by AIBN: Optimization, Scope and Radical Reaction Pathways.

✍ Scribed by Piotr Balczewski; Aldona Szadowiak; Tomasz Bialas

Publisher
John Wiley and Sons
Year
2006
Weight
19 KB
Volume
37
Category
Article
ISSN
0931-7597

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The iodine atom transfer addition reacti
The iodine atom transfer addition reaction (I-ATRA) initiated by AIBN: Optimization, scope and radical reaction pathways
✍ Piotr Bałczewski; Aldona Szadowiak; Tomasz Białas 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 206 KB

## Abstract Optimization of reaction conditions (alkene, halide, solvent, stoichiometry, manners of the reagents addition, and reaction time) of the I‐ATRA reactions involving 1‐iodoalkylphosphonates was carried out. GC–MS–CI/EI analyses showed main and side products of this reaction and the corres

Two pathways of initiation in the interm
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## Detection of 4-iodo-2,2-dimethyloctanenitrile and 2-iodo-2-methylpropanenitrile proved an operation of two types (I and II) of initiation in the I-ATRA reaction. 4-Iodo-2,2-dimethyloctanenitrile, resulting from the isobutyronitrile radical attack onto 1-hexene followed by the iodine atom transfer