The investigation of ion—formamide interactions by ab initio model calculations
✍ Scribed by Karol Miaskiewicz; Joanna Sadlej
- Book ID
- 119116247
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 540 KB
- Volume
- 124
- Category
- Article
- ISSN
- 0166-1280
No coin nor oath required. For personal study only.
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## Abstract The neutral hydrolysis of formamide in water is a suitable reference to quantify the efficiency of proteolytic enzymes. However, experimental data for this reaction has only very recently been obtained and the kinetic constant determined experimentally is significantly higher than that
The energies of the hydrated I3r-ion for coordination numbers up to 4 hate been calculated with an ab initio hf0 method. The most favorable orientation is the ion-dipole one. in contrast to the H-bonded orientation for C17HaO) and F7HzO). The hydration energies cafcufa~ed in this study are in fair