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The ?inverse electron-demand? Diels?Alder reaction in polymer synthesis. Part 2. Some bis(1,2,4-triazines) as potential bis-diene monomers

✍ Scribed by Bruce, Michael J.; McLean, Gillian A.; Royles, Brodyck J. L.; Smith, David M.; Standring, Paul N.


Book ID
120322643
Publisher
Royal Society of Chemistry
Year
1995
Weight
903 KB
Volume
14
Category
Article
ISSN
1472-7781

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The Diels-Alder reaction of 5,5 -bi-1,2,4-triazines with cyclic enamines in the absence of a solvent leads to a range of symmetrical, annulated 2,2 -bipyridines in good yield. When the reaction is carried out in boiling dioxane only 5-(heteroaryl)1,2,4-triazines are formed. The latter, bearing methy