The invention of radical reactions. Part XXXV. A novel radical fission reaction of N-sulfonylthioxocarbamates
โ Scribed by Derek H.R. Barton; Giovanni Fontana; Yun Yang
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 697 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
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Irradiation with visible light of N-hydraxy-2-thiopyridone esters f in the presence of sulphur dioxidrgave the corresponding th~os~fp~o~otes 4 in good yiefd. These could be converted to s&phones 5 by-treatment with KOH and an alkylating ogent. Alternatively, exposure to sulphuryl chloride followed b
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