The Intramolecular Thermal Rearrangement of the Bicyclo[3.2.0]Heptenyl to the Bicyclo[2.2.1]Heptenyl System
β Scribed by Berson, Jerome A.; Patton, James W.
- Book ID
- 126867983
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 246 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Brcyclo(3.2.0)heptenyl radicals rearrange In matrix to cyclopentadlenyl and cyclohexadienyl radicals.
## Abstract The tricyclic lactams 4aβh, possessing a bicyclo[2.2.2]octadiene moiety, obtained by intramolecular DielsβAlder reaction of the vinylidene malondiamides 1aβh, generally isomerize in boiling xylene to give the new lactams 7aβh, now bearing a bicyclo[3.2.1]octadiene part. The difference i
It has been reported that irradiation of tropolone methyl ether (Ia) and its alkyl derivatives provided first their valence isomers, the l-methoxy-d'6 -bicycle (3.2.O)heptadien-2-ones (II), which in turn, on futher irradiation, isomerized to the 7-methoxyl derivatives (III).2 In this case, other va