The Intramolecular Isotope Effect in the Pyrolysis of 1-14C Propane
β Scribed by H. M. Frey, C. J. Danby and Cyril Hinshelwood
- Book ID
- 123675547
- Publisher
- The Royal Society
- Year
- 1956
- Tongue
- English
- Weight
- 258 KB
- Volume
- 234
- Category
- Article
- ISSN
- 0962-8444
- DOI
- 10.2307/99835
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π SIMILAR VOLUMES
The thermal decomposition of deuterated ethyl chloride CHzDCHzCl was studied in a static system in the pressure range of 0.1-26 torr, and the Arrhenius expression for the overall decomposition at the high-pressure limit and in the temperature range of 670-1100 K was found to be k , = 1013.33\*0.10 e
The thermal unimolecular decomposition of diethyl carbonate-1,1,1,2,2-d5 has been examined in the high-pressure-limiting region. The observed chemistry is consistent with a simple, competitive two-channel model: The intramolecular isotope effect k H / k D has been determined, and the relative Arrhe