𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The intramolecular Diels-Alder reaction: Stereocontrol through nonsynchronous bond formation?

✍ Scribed by Douglass P. Taber; Carlton Campbell; Bruce P. Gunn; I-Ching Chiu

Book ID
104243559
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
178 KB
Volume
22
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Nonsynchronous bond formation in the transition state of the intramolecular Diels-Alder reaction is suggested to be an important determinant of the stereochemical outcome of the cyclization.

📜 SIMILAR VOLUMES

Stereocontrol of the Intramolecular Diel
Stereocontrol of the Intramolecular Diels−Alder Reaction by Internal Hydrogen Bonding
✍ Tory N. Cayzer; Michael N. Paddon-Row; Michael S. Sherburn 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 223 KB

## Abstract A novel approach for __exo__/__endo__ stereocontrol of intramolecular Diels−Alder reactions is described. Substrates carrying a hydroxymethyl group attached to the diene and an ester group attached to the dienophile participate in hydrogen bonding in the transition state. This non‐coval