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The intramolecular charge-transfer interaction in N-[ω-(p-nitrophenyl)alkyl]anilines

✍ Scribed by Michinori Ōki; Kiyoshi Mutai


Book ID
104249642
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
217 KB
Volume
9
Category
Article
ISSN
0040-4039

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✦ Synopsis


In the study of intramolecular N-H...n interaction, certain forces, such as intramolecular charge-transfer (CT) complex formation, have been euggested to be operating in some homologs (I) of N-(p-nitrobenzyl)aniline (2).


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AM1 study of the twisted intramolecular
✍ T. Soujanya; G. Saroja; A. Samanta 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 689 KB

The twisted intramolecular charge transfer phenomenon in p-(N,N-dimethylamino)benzonitrile has been studied using Austin model 1 (AMI) semi-empirical calculations. A detailed picture of the twisting process is obtained by calculation of the ground and excited state profiles as a function of twist an