The intramolecular charge transfer in a donor–π–acceptor dianion probed by resonance Raman spectroscopy and quantum chemical calculations

✍ Scribed by Rômulo A. Ando; Antonio C. Borin; Paulo S. Santos

• Publisher: John Wiley and Sons
• Year: 2009
• Tongue: English
• Weight: 129 KB
• Volume: 40
• Category: Article
• ISSN: 0377-0486
• DOI: 10.1002/jrs.2250

✦ Synopsis

Abstract

The dideprotonation of 4‐(4‐nitrophenylazo)resorcinol generates an anionic species with substantial electronic π delocalization. As compared to the parent neutral species, the anionic first excited electronic transition, characterized as an intramolecular charge transfer (ICT) from the CO^−^ groups to the NO~2~ moiety, shows a drastic red shift of ca. 200 nm in the λ~max~ in the UV‐vis spectrum, leading to one of the lowest ICT energies observed (λ~max~ = 630 nm in dimethyl sulfoxide (DMSO)) in this class of push‐pull molecular systems. Concomitantly, a threefold increase in the molar absorptivity (ε~max~) in comparison to the neutral species is observed. The resonance Raman enhancement profiles reveal that in the neutral species the chromophore involves several modes, as ν(CN), ν(NN), ν(CC) and ν~s~(NO~2~), whereas in the dianion, there is a selective enhancement of the NO~2~ vibrational modes. The quantum chemical calculations of the electronic transitions and vibrational wavenumbers led to a consistent analysis of the enhancement patterns observed in the resonance Raman spectra. Copyright © 2009 John Wiley & Sons, Ltd.