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The Interpretation of the Terminal ν(CO) Spectra of Some Tetranuclear Carbonyl Clusters

✍ Scribed by Sidney F. A. Kettle; Eliano Diana; Enrico Boccaleri; Pier Luigi Stanghellini


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
264 KB
Volume
1999
Category
Article
ISSN
1434-1948

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✦ Synopsis


The recently suggested spherical (SHM) and tensor (THM) appropriate as a first approximation. The distinction between the two appears to be associated with a disruption of the harmonic models are applied to the interpretation of the terminal ν(CO) spectra of twenty six tetrahedral transition band structure of the cluster either by the introduction of heterometal atoms or by the presence of a group -acetate metal clusters containing between four and twelve terminal carbonyl groups. Although the SHM is perhaps the more ester, halide or hydride -presumably acting as an electronegative substituent. generally relevant, there are species for which the THM is illustrated in Figure , where we give the expected qualitat-


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