The interpretation of the stability of aromatic hydrocarbon ions by valence bond theory
β Scribed by H. Fischer; J. N. Murrell
- Publisher
- Springer
- Year
- 1963
- Tongue
- English
- Weight
- 260 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1432-2234
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π SIMILAR VOLUMES
It is shown using simple perturbation theory that the intermoleculara-electron interaction leads to stabilisation of aromatic hydrocarbon dirners of certain tilted configuration ti th respect to two infinitely isolated monomers. The condition of stability of these dimers is the occurrence of lowlyin
The use of orthogonalized atomic orbitals in valence bond type wavefunctions ts critically examined. By analyzing a test case m detatl, it is shown that the simple interpretation of such wavefunctions in terms ofweighted chemical formulae can be misleading.
## Abstract Previous papers have developed magnetic effective valence bond (EVB) Hamiltonians for the neutral states of Ο systems; following the same philosophy and using either the quasidegenerate perturbation theory or wave operator formalism, other EVB^+^ Hamiltonians may be derived for the lowe