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The Interlocked Structure of a New Thiophosphate of Transition Metal CrP3S9+x (x ≈ 0.25)

✍ Scribed by P. Fragnaud; M. Evain; E. Prouzet; R. Brec

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
311 KB
Volume
102
Category
Article
ISSN
0022-4596

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A vibrational study of \(\mathrm{CrP}_{3} \mathrm{~S}_{9.25}\) was undertaken in order to confirm the substitution of some \(\mathrm{S}^{2 \cdot}\) anions by \(\left(\mathrm{S}_{2}\right)^{2-}\) pairs as focused by a \(X\)-ray single-crystal analysis. Comparison between the infrared and Raman spectr

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The Crystal Structure of Kx(MgxIn1–x)F3 (x = 0.38): a New Magnéli-Bronze Type Fluoride
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K x (Mg x In 1±x )F 3 (x = 0.38) is monoclinic, pseudo tetragonal: a = 12.781(2) A Ê , b = 12.787(2) A Ê , c = 7.930(1) A Ê , b = 90,00(1)°, Z = 20. The crystal structure was solved in the space group P2 1 /a (No. 14), subgroup of the tetragonal space group P4/mbm (No. 127), from X-ray single crysta