η1-Vinylidene to η2-Alkyne Isomerization
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Junes Ipaktschi; Javad Mohsseni-Ala; Sascha Uhlig
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Article
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2003
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John Wiley and Sons
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English
⚖ 175 KB
## Abstract The thermal isomerizations of η^1^‐vinylidene complexes [(η^5^‐C~5~H~5~)(CO)(NO)W=C=CHR] [5a, R = Si(CH~3~)~2~C(CH~3~)~3~; 5c, R = C(CH~3~)~3~] as well as [(η^5^‐C~5~H~5~)(CO)(NO)Mo=C=CHC(CH~3~)~3~] (8), to the corresponding η^2^‐1‐alkyne complexes [(η^5^‐C~5~H~5~)(CO)(NO)W(η^2^‐H−C≡C−R