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The intercalation to DNA of bipyridyl complexes of platinum(II) with thioureas

✍ Scribed by Matteo Cusumano; Maria Letizia Di Pietro; Antonino Giannetto; Pasquale Antonio Vainiglia

Book ID
108174833
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
310 KB
Volume
99
Category
Article
ISSN
0162-0134

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The Reaction of (Bipyridyl)palladium(II)
The Reaction of (Bipyridyl)palladium(II) Complexes with Thiourea − Influence of DNA and Other Polyanions on the Rate of Reaction
✍ Matteo Cusumano; Maria Letizia Di Pietro; Antonino Giannetto; Pasquale Antonio V 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 157 KB

## Abstract [Pd(bipy)(py)~2~](PF~6~)~2~ reacts stepwise with excess thiourea to give [Pd(tu)~4~](PF~6~)~2~. The kinetics of the second step, which refers to the replacement of bipyridyl in [Pd(bipy)(tu)~2~](PF~6~)~2~, have been studied in water and in the presence of calf thymus DNA, sodium polyrib