✦ LIBER ✦

The interaction of γ-glycidoxypropyltrimethoxy silane and model analogues with the Al(1 1 1) surface

✍ Scribed by G.A. Woods; S. Haq; S.J. Shaw; R. Raval

Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 388 KB
Volume: 26
Category: Article
ISSN: 0143-7496
DOI: 10.1016/j.ijadhadh.2003.06.002

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✦ Synopsis

The adsorption characteristics of three organosilane compounds on a model Al(1 1 1) surface has been investigated using reflection-absorption infrared spectroscopy (RAIRS). The three compounds considered, epoxyhexane (EH), glycidylisopropylether (GIE) and g-glycidoxypropyltrimethoxysilane (g-GPS) have demonstrated adsorption behaviour dependent upon both the extent of coverage and temperature. Both EH and GIE have shown that, under certain conditions, they can interact with the Al(1 1 1) surface via their glycidyl groups. With g-GPS, the glycidyl group adopts a slightly altered geometry from that in EH and GIE, thus enabling some of the methoxy groups to be directed towards the Al(1 1 1) surface.

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The interaction of γ-glycidoxypropyltrimethoxy silane and model analogues with the Al(1&#xa0;1&#xa0;1) surface

✦ Synopsis

The interaction of γ-glycidoxypropyltrimethoxy silane and model analogues with the Al(1 1 1) surface