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The interaction of native DNA with iron(III)-N,N′-ethylene-bis(salicylideneiminato)-chloride

✍ Scribed by Arturo Silvestri; Giampaolo Barone; Giuseppe Ruisi; Maria Teresa Lo Giudice; Salvatore Tumminello


Book ID
108174764
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
249 KB
Volume
98
Category
Article
ISSN
0162-0134

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The reaction of (diaqua)(N,NЈ-ethylene-bis(salicylidiniminato)manganese(III) with aqueous sulphite buffer results in the formation of the corresponding mono sulphito complex, [Mn(Salen)(SO 3 )] Ϫ (S-bonded isomer) via three distinct paths: (i) Mn(Salen)(OH 2 ) 2 ϩ ϩ HSO 3 Ϫ : (k 1 ); (ii) Mn(Salen)(