The interaction of metallophthalocyanines with electron-acceptor metal chlorides

✍ Scribed by Ewa Białkowska; Alfreda Graczyk

• Publisher: John Wiley and Sons
• Year: 1978
• Tongue: English
• Weight: 379 KB
• Volume: 11
• Category: Article
• ISSN: 0749-1581
• DOI: 10.1002/mrc.1270110403

✦ Synopsis

It has been found that interactions of metallophthalocyauines with chlorides having electron-acceptor

properties results in the formation of charge transfer complexes of an ion-pair nature. The electronic structure of these complexes and the mechanism of the interaction were studied by the EPR method. Spin-Hamiltonian parameters were determined and the effect of the complex-forming substance on the nature of the EPR spectrum was analysed. The experimental EPR results were correlated with the effective magnetic moments determined from measurements of magnetic susceptibility by the NMR method.