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The interaction of hexaphenylcarbodiphosphorane with the trimethylplatinum(IV) cation

โœ Scribed by Baldwin, James C.; Kaska, William C.


Book ID
126874617
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
863 KB
Volume
18
Category
Article
ISSN
0020-1669

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Electrochemical reduction of the trimeth
โœ D.R. Rosseinsky; K. Kite; T.D. Phillips ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science โš– 85 KB

Reductive polarograms, initially obtained by Rosseinsky and Kite 1 , showed four waves, which could have indicated a separate wave for the reduction of each platinum oxidation state in the process (IV) -~ (0). It was recognised 1 that the final wave at -1.8 V (vs. 0.5 M Na2 SO4/Hg2 SO4/Hg) could hav