We report the electrochemical formation of Pt particles on fluorine-doped tin oxide electrodes by varying the concentration of PtCl 4 2-ions and the overpotentials within the mass-transfer-limited region. The nucleation mechanisms are considered based on the results obtained by cyclic voltammetry, c
The interaction of different oxidizing agents on doped tin oxide
✍ Scribed by I. Sayago; J. Gutie´rrez; L. Are´s; J.I. Robla; M.C. Horrillo; J. Getino; J.A. Agapito
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 307 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0925-4005
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✦ Synopsis
The interaction of NO*, NO= and O2 on an SnO, thin-film surface is studied. Experiments have been carried out for different tin-oxide films, undoped and doped with Pt, In and Al, prepared by reactive sputtering (r.f.) on alumina substrates. These films should allow the development of detectors for nitrogen oxides at concentrations of about a few ppm. Conductance measurements have been done in a constant flow of inert atmosphere (NJ and in synthetic air containing oxidizing agents (NO? and NO,) to study directly adsorbed NOz and NO and their reaction with chemisorbed oxygen. The results are discussed in terms of surface reactions.
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