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The interaction of aquated cis-[(NH3)2Pt(II)] with nucleic acid constituents. II. modified nucleosides

✍ Scribed by T. O'Connor; W.M. Scovell

Book ID: 113136005
Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 403 KB
Volume: 26
Category: Article
ISSN: 0009-2797
DOI: 10.1016/0009-2797(79)90026-7

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In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking