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The Interaction between the Lone Pairs in Azomethane

โœ Scribed by Dr. E. Haselbach; Dr. J. A. Hashmall; Prof. Dr. E. Heilbronner; Dipl.-Chem. V. Hornung


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
135 KB
Volume
8
Category
Article
ISSN
0044-8249

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## Abstract Calculations on phosphole systems using the G3MP2B3 model chemistry show that the phosphorus lone pair is critical to the system's aromaticity. Protonation of the lone pair results in antiaromatic molecules as measured by homomolecular homodesmotic reactions. Attempts to separate out ef