✍ Scribed by Ulf Edlund; Hans Grahn
No coin nor oath required. For personal study only.
The ^13^C spin‐lattice relaxation times for carbon tetrachloride have been measured in the presence of various paramagnetic chromium (III) chelates (PARRs). The T~1~ values were compared with those of an inert standard, cyclohexane. A specific PARR: carbon tetrachloride interaction was clearly indicated, which is less obvious for bulky ligands or ligands having electron‐withdrawing substituents. The electron‐nuclear relaxation model and the quantitative description of outer‐sphere complexation is briefly discussed.
📜 SIMILAR VOLUMES
A metathetical reaction between carbon tetrachloride and toluene to give benzyl chloride and chloroform occurs at temperatures above 200°C (k = 4.8 X 1Olo e-82,m/RT cc mole-'sec-'). The reaction does not involve free radicals, as is shown by the kinetic behavior of the system, by the lack of effect
## Abstract The genotoxic potential of the administration of carbon tetrachloride alone or carbon tetrachloride to chlordecone‐pretreated rats was investigated using an __in vivo–in vitro__ animal model and a battery of biochemical assays to measure DNA repair in rat hepatocytes. Whereas carbon tet