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The intensity of the R0(0) transition of solid HD

โœ Scribed by A.R.W. McKellar; M.J. Clouter

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
287 KB
Volume
140
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The R&O) pure rotational transition of solid hydrogen deuteride in the far infrared (88 cm-') has been measured using a Fourier transform infrared spectrometer. The line strength (integrated absorption) of this transition was found to be in good agreement with the result of a recent calculation, but considerably larger than that measured in the only previous experiment. A strong dependence of the linewidth of the R,( 0) feature on the isotopic sample purity was observed for liquid HD, and the same effect may be present in the solid.

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