## Abstract Work on the oxidation of carbonaceous materials with alkaline potassium permanganate is briefly outlined and the experimental stepβwise oxidation of free carbon is described. The course of reaction as interpreted from these results is indicated. Bulk oxidation of free carbon and the nat
The insoluble matter of coal tar III. Some inorganic constitutents of free carbon
β Scribed by Green, S. J. ;Thakur, B.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1948
- Weight
- 282 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0368-4075
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
The inorganic constituents of coals are bricfly reviewed and their subsequent history during combustion and carbonization is considered. The cxamination is reported of the zincβpyridine complex obtained from a free carbon sample by extraction with water. Examination for other elements is described and the presence of lead, iron, cobalt, manganese and others indicated. The form in which these elements are present is discussed.
π SIMILAR VOLUMES
## Abstract The effect of previous conditions of preparation and storage of coal tars on the amount of fre carbon determined by insolubility in toluene has been investigated. Pressure is shown to have little effect but at atmospheric pressure there is progressive increase in free carbon. With risin
## Abstract The Soβcalled coal tar resins are defined and their preparation from vertical retort tar and pitch is described. The resins are divided into resinols, resinoic acids, resinenes, and resinamines, about 99% consisting of resinenes. The importance of dxygen in these compounds is discussed.
## Abstract Further work on resinenes is reported including hydrolysis, bromination, thermal decomposition, dehydrogenation, hydrogenation, and alk line permanganate oxidation. The resinenes give neutral and phenolic products on hydrolysis. Dehydrogenation with selenium gives neutral and phenolic p
## Abstract Various methods available for the determination of the insoluble matter of coal tar are briefly reviewed and published work on the nature of free carbon and the coalβtar resins is considered. The problems associated with free carbon are introduced and the scope of the investigation prop