The variations of the geometrical (bond lengths and angles), electronic (dipole moment magnitude and orientation) and chemical (acidity) data whi-h are experimentally observed when going from the cis to the frets isomer of nitrous acid are fully reproduced within the fmmework of semi-empiricnl CNDO/
The infrared vibration—rotation spectrum of trans and cis nitrous acid
✍ Scribed by C.M. Deeley; I.M. Mills
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 898 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0022-2860
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The pore rotational absorption spectrnk of nit& acid vapour has been observed in the &ion S-40 cm-' at a ' . 'Ie.wlution of 0.05 cm-l , using the technique of Fourier transform spdrometry. The structure of the spectrum is of considerabIe kterest, since it corresponds ciosely to the normally forbidde