The Infrared Spectrum of Acetylene-d 11
β Scribed by Allen, Harry C.; Tidwell, Eugene D.; Plyler, Earle K.
- Book ID
- 126882515
- Publisher
- American Chemical Society
- Year
- 1956
- Tongue
- English
- Weight
- 581 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The infrared spectrum of acetylene trimer has been obtained in the 3 urn wavelength region by observing direct absorption of color center laser radiation by a pulsed molecular beam. The rotational structure of this band was that of a planar oblate symmetric top. The B rotational constant is 1885.8 M
Rotationally resolved infrared spectra are reported for the T-shaped acetylene-HF complex in helium nanodroplets, corresponding to excitation of both the H-F and asymmetric C-H stretches. In comparison to the isolated complex, rotation about the A-axis is relatively unhindered by the helium, while o