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The Infrared Spectra of N-Substituted Trifluoroacetamides

โœ Scribed by Robson, John H.; Reinhart, Joan


Book ID
127207222
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
258 KB
Volume
77
Category
Article
ISSN
0002-7863

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Preparation of secondary amines through
โœ J.Eric Nordlander; David B. Catalane; Thomas H. Eberlein; Lee V. Farkas; Robert ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 223 KB

Trifluoroacetamides are attractive intermediates for the Gabriel-like1 transformation of primary to secondary amines through a sequence of acylation, ionization, alkylation, and hydrolysis. Overalkylation is precluded, and the trifluoroacetyl group is readily introduced' to furnish a carboxamide of