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The Infrared Laser Spectrum of the 101211 Hot Band of CCN

✍ Scribed by S.A Beaton; D.A Gillett; J.M Brown; M Fehér; A Rohrbacher

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
188 KB
Volume
209
Category
Article
ISSN
0022-2852

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✦ Synopsis

The 1 1 0 2 1 1 band of the CCN radical in the ground 2 state has been recorded by tunable diode laser spectroscopy. Two of the three Renner-Teller subbands of this transition have been assigned and analysed. A series of doublets is assigned as the 1 1 0 2 1 1 µ 2 (-) band, and both spin-orbit components of the 1 1 0 2 1 1 2 band have been observed. The data have been analyzed using an effective N 2 Hamiltonian modified to include the Renner-Teller effect explicitly in a 2 state. The 1 1 0 2 1 1 κ 2 (+) band could not be identified from the data; possible reasons for this are discussed.

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