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The infrared enhanced multiphoton ionization mass spectrum of 1,1,1-trichloroethane

✍ Scribed by James H. Glownia; Robert J. Romero; Robert K. Sander

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 346 KB
Volume: 88
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)87090-5

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✦ Synopsis

The multiphoton ionization (MPI) mass spectrum of 1,1,1-trichloroethane has been observed at 266 nm. A three-fold enhancement in the signal is observed due to vibrational excitation of 1,1,1-trichloroethane with a CO2 laser. The infrared enhanced MPI spectrum shows a different fragmentation pattern than does 1,1-dichloroethylene, which would be the product of infrared multiphoton dissociation.

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