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The infrared absorption spectrum of a supersonic expansion of methyl chloride

✍ Scribed by Deanne L. Snavely; Kenneth B. Wiberg; Steven D. Colson

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 403 KB
Volume: 96
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80681-2

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✦ Synopsis

The infrared absorption spectrum of a rotationally cooled supersonic jet of neat methyl chloride is reported. The rotational constants of 13, ~2 and ~1 are determined. Using a 0.05 mm nozzle diameter and a 2 atm sta_aation pressure, a Boltzmann population distribution is found with a characteristic rotational temperature of 120 K:.

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