The Influence of Unsaturation and of Fluorine Substitution on Ketone-Alcohol Equilibrium Constants. A Measure od α,β-Unsaturated Ketone Resonance Energy and of Halogen Destabilization

ChemInform Abstract: A New Halogen-Excha

ChemInform Abstract: A New Halogen-Exchange Reaction Between Sn—F and Li—X: Selective 1,2- and 1,4-Reductions of α,β-Unsaturated Ketones and Effects of Halogen Substituents on the Regioselectivity of Organotin Hydrides.

✍ Takayo Moriuchi-Kawakami; Haruo Matsuda; Ikuya Shibata; Masato Miyatake; Toshihi 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

A New Halogen-Exchange Reaction Between Sn-F and Li-X: Selective 1,2-and 1,4-Reductions of α,β-Unsaturated Ketones and Effects of Halogen Substituents on the Regioselectivity of Organotin Hydrides. -In dependence of the additive a highly regioselective reduction is obtained under optimized condition