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The influence of time dependence of temperature on the kinetics of nucleation

✍ Scribed by Z. Kožíšek; Z. Chvoj

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
302 KB
Volume
18
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

In this work the influence of time dependence of temperature on kinetic processes during nucleation on a simple model is studied. The nucleation rate and the average effective radius of nuclei R is counted. It is proved that in the case of oscillating temperature the nucleation rate also oscillates and the rate of growth of radius R is directly proportional to frequency of temperature change.

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## Abstract The temperature dependence of the oxygen reduction kinetics on carbon‐supported Ru~x~Se~y~ catalysts is studied using a rotating disc electrode in 0.5 M H~2~SO~4~ in the temperature interval from 25 °C to 65 °C. When the absolute value of the overpotential is below ca. 0.65 V, the react