The Influence of the Underlying Gold Substrate on Glucose Oxidase Electrodes Fabricated Using Self-Assembled Monolayers
β Scribed by D. Losic; J. J. Gooding; J. G. Shapter; D. B. Hibbert; K. Short
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 829 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1040-0397
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The influence of bromine adsorption on copper electrodeposition on a polycrystalline gold electrode modified with self-assembled monolayers (SAMs) has been investigated by chronoamperometry and cyclic voltammetry. It was found that the deposition potential of copper was shifted negatively due to the
Cyclodextrin derivatives modified with seven thioether moieties (1) or with one thiol moiety (2) bind to gold. Monolayers on gold of 1 or mixed monolayers of 2 and mercaptoundecanol were characterized by electrochemistry, wettability, and atomic force microscopy (AFM). Monolayers of 1 are well-order