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The influence of the symmetry of the vibrations on resonance raman intensities

โœ Scribed by Daniel van Labeke; Marcel Jacon; Lucien Bernard

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
258 KB
Volume
27
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Resonance

Raman intensity theory is invcstigaled by using the 6 approximalion as a basis. The influence of the transition moment derivatives is studied. Two kinds of vibrations, A and S. are then considered by the authors. It is shown that the S vibrations (generally totnlly symmetric vibrations) arc more enhanced that the A ones and arc the only vibrations which may exhibit a large progression of overtones in the remnance region.

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Effects of hydration on the structure, v
Effects of hydration on the structure, vibrational wavenumbers, vibrational force field and resonance raman intensities of N-methylacetamide
โœ Hajime Torii; Tomoaki Tatsumi; Mitsuo Tasumi ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 305 KB ๐Ÿ‘ 2 views

The e โ€ ects of hydration on the structure and vibrational force รeld of the peptide group were examined by performing ab initio molecular orbital (MO) calculations on N-methylacetamide (NMA) and its clusters with up to three water molecules. The dielectric solvent e โ€ ect was taken into account by th