The Influence of the Ring Size of Thiolactams in the Eschenmoser Coupling Reaction in Presence of DBU. Formation of Bicyclic Thiazolidinones or Thioimines.
β Scribed by Dennis Russowsky; Brenno Amaro da Silveira Neto
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 113 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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## Abstract A highly regioselective synthesis of bicyclic sulfamides is described. Based on our recent discovery that bromoallenes can act as allyl dication equivalents in the presence of a palladium catalyst and alcohol, we investigated tandem cyclization of bromoallenes bearing a sulfamide group.