𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Influence of the Leaving Group X (X=F, Cl, Br, I, OH) on the Carbenoid Nature of the Carbenoids LiCH2X and XZnCH2X—A Theoretical Study

✍ Scribed by Holger Hermann; John C.W. Lohrenz; Andreas Kühn; Gernot Boche


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
131 KB
Volume
56
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis


Dedicated to Professor Rolf Huisgen on the occasion of his 80th birthday


📜 SIMILAR VOLUMES


Ab initio studies on the structures and
✍ Huayu Qiu; Conghao Deng 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 304 KB

The potential energy surface of the singlet carbenoid H2CLiCI has been examined using ab initio methods including electron correlation. The 6-31G \* basis set was used for all geometry optimizations. Three equilibrium structures and two isomeric transition states were located, but only the lowest en

A comprehensive theoretical study on the
✍ Yi Ren; San-Yan Chu 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 244 KB

Gas phase identity ion pair S N 2 reactions at nitrogen LiX + NH 2 X ! XNH 2 + LiX (X ¼ F, Cl, Br and I) are investigated at the G2M(+) level. Two reaction mechanisms, inversion and retention, are proposed. Results indicate the inversion mechanism is favorable for all halogens. Including Li in the a