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The Influence of Tertiary Amine Structure On Blow-To-Gel Selectivity

✍ Scribed by Listemann, M.L.; Wressell, A.L.; Lassila, K.R.; Klotz, H.C.; Johnson, G.L.; Savoca, A.C.

Book ID
121478362
Publisher
SAGE Publications
Year
1993
Tongue
English
Weight
159 KB
Volume
29
Category
Article
ISSN
0021-955X

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πŸ“œ SIMILAR VOLUMES

Selective reduction of secondary amides
Selective reduction of secondary amides to amines in the presence of tertiary amides
✍ Byung H. Lee; Michael F. Clothier πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 89 KB

Secondary amides activated with a Cbz group can be reduced to their corresponding hemiaminals using lithium borohydride. Hydrogenation then removes the Cbz and hydroxyl groups to produce the related amine. Tertiary amides are not affected.