The influence of temperature and surface composition upon the coordination of acetone to the Pd(111) surface
โ Scribed by J.L. Davis; M.A. Barteau
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 75 KB
- Volume
- 208
- Category
- Article
- ISSN
- 0167-2584
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The coadsorption of C,H, with Hz and CO on Pd(ll1) has been investigated at 300 and 330 K\_ At 300 2; two forms of adsorbed ethylene coexist on the surface in the presence of ethylene gas: a molecular iorm desorbing 3s C2 & at 330 K and a dissociatively adsorbed form (giving only hydrogen in dcsorpt
Processes occurring during dosing of ketene on a heated Pt(ll1) surface were investigated using high-resolution electron energy loss spectroscopy and temperature-programmed desorption. During dosing at 400 K, CO and Hz are evolved and ethylidyne accumulates on the surface. In contrast, at 350 K a Cx