The influence of solvation on the calculated activation energy for the reaction CH3F+F−
✍ Scribed by P. Cremaschi; A. Gamba; M. Simonetta
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 453 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1432-2234
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The simplified statist&l adiabatic channel model is used to calculate the limitins high-pressure rate constant of the thermal recombmatron-dxisociatlon reaction H + CH3 \* CH.+ The dependence of the rate constant on the chxacteristic parameters of the radial and angular parts of the H-CH3 interactio
The effect of electron correlation on the energy profile of an SR2 gas-phase reaction is studied within Brauman's double-well model. Correlation ~n~~utions to the well depth, intrinsic and overall bar&Is and the heat of reaction are ~lc~~d using complete fourth-order MBPT. It is shown that electron