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The influence of silicon and yttrium on isothermal scaling of an austenitic Fe-Cr-Ni alloy (IN 519) at 1000 °C

✍ Scribed by D. J. Baxter; R. T. Derricott; R. C. Hurst


Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
645 KB
Volume
34
Category
Article
ISSN
0947-5117

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✦ Synopsis


When present in austenitic Fe-Cr-Ni alloys, both silicon and yttrium influence scaling behaviour during oxidation tests in air at high temperatures. The former promotes the formation and maintenance of a continuous Crz03 scale and the latter improves scale adhesion. During the isothermal exposure of nominally Fe + 24%Cr + 24%Ni cast alloys at 1000 "C a silicon content above 0.8% reduces the rate of scaling by providing additional sites for the lateral growth of the Crz03 layer. Yttrium gives rise to the formation of Fe9Y particles which disrupt the continuity of the CrzO, scale. The beneficial influence of silicon dominates the potentially detrimental effect of yttrium in alloys containing both silicon and yttrium.

Sowohl Silizium als auch Yttrium beeinflussen das Verzunderungsverhalten von austenitischen FeCrNi-Legierungen in Luft hoher Temperatur. Silizium fordert die Bildung und Erhaltung eines kontinuierlichen Chromoxidzunders, wahrend Yttrium die Haftfestigkeit der Zunderschicht erhoht . Unter isothermischen Bedingungen wird bei 1000 "C durch mindestens 0,8% Silizium die Verzunderungsgeschwindigkeit der GieBlegierung Fe 24 Cr 24 Ni dadurch verringert, daB zusatzliche Zentren fur die seitliche Ausbreitung der Chromoxidschicht geschaffen werden. Yttrium fiihrt zur Bildung von Fe9Y-Teilchen, welche die Kontinuitat der Chromoxidschicht unterbrechen. Der giinstige EinfluR des Siliziums iibenviegt bei den potentiell schadlichen Wirkungen des Yttriums in Legierungen, die beide Elemente enthalten.


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The influence of silicon and yttrium on
✍ D. J. Baxter; R. C. Hurst; R. T. Derricott 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 587 KB

Data obtained using thermogravimetric and resonant frequency techniques and the results of structural analysis are used to evaluate the effects on oxidation of silicon andlor yttrium additions to an Fe-24% Cr-24% Ni alloy tested under thermal cyclling conditions. Silicon promotes the formation of a