Scaling theory is applied to derive expressions describing the influence of polymolecularity on the second virial coefficient, A , , as obtained from osmotic pressure and light scattering measurements. Numerical values of polymolecularity correction factors are calculated for Schulz-Zimm and logarit
β¦ LIBER β¦
The influence of polymolecularity on thermodynamic properties of macromolecular systems
β Scribed by R. Koningsveld
- Book ID
- 104520683
- Publisher
- Society for Plastic Engineers
- Year
- 1985
- Tongue
- English
- Weight
- 128 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0032-3888
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## Abstract It is shown that the recently developed scaling theory for the second virial coefficient, __A__~2~, of dilute solutions of polymers with nonβuniform molecular weight distributions in a good solvent is able to explain in principle all seemingly contradictory observations reported in the
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