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The Influence of Oxalate on Fe-Catalyzed S(IV) Oxidation by Oxygen in Aqueous Solution

✍ Scribed by A. Wolf; F. Deutsch; P. Hoffmann; H. M. Ortner

Book ID: 110235693
Publisher: Springer Netherlands
Year: 2000
Tongue: English
Weight: 92 KB
Volume: 37
Category: Article
ISSN: 0167-7764
DOI: 10.1023/a:1006462025384

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## Abstract To understand the chemistry of Cu(II)–NH~3~–S(IV)–O~2~ system, the kinetics of the oxidation of sulfur(IV) catalyzed by amminecopper(II) complexes has been studied in the ammonia‐buffered solutions. Sulfur(IV) is oxidized to sulfate. The complexes, Cu(NH~3~)^2+^, Cu(NH~3~)~2~^2+^, and C