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The influence of non-adiabaticity on the nuclear motion in the H3+ molecule

✍ Scribed by Ralph Jaquet


Book ID
108312783
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
429 KB
Volume
302
Category
Article
ISSN
0009-2614

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On the theory of non-adiabatic effects i
✍ E. Deumens; L. Lathouwers; P. Van Leuven πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 354 KB

It is shown that the generator coordinate approximation introduces non-adiabatic effects of the correct sign (ener,g lowerinrz) and size (Born-Oppenheimer analysis)\_ The theoretical expression applied to diatomic molecules qualitatively explains the observed trends of non-adiabatic energy correctio