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The influence of methemoglobinemia on the lethality of some toxic anions: I. Azide

✍ Scribed by Roy A. Abbanat; Roger P. Smith


Book ID
119000655
Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
572 KB
Volume
6
Category
Article
ISSN
0041-008X

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Treatment of isotopically labeled bromophenyldiazirine containing one 15N atom with azide ion produces benzonitrile which contains 50% 15N. This suggests that N-azidodiazirines are intermediates in the reaction. Ab initio calculations predict that N-azidodiazirines will have a very low barrier to de